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Manipal MET2016Chemistryd and f Block Elements

The electronic configurations of chromium (at. no. 24) and copper (at. no. 29) are

Options

  1. A[ Ar ] 4 s^1 3 d^5 and [ Ar ] 4 s^1 3 d¹⁰
  2. B[ Ar ] 4 s^2 3 d^4 and [ Ar ] 4 s^1 3 d¹⁰
  3. C[ Ar ] 4 s^1 3 d^5 and [ Ar ] 4 s^2 3 d^9
  4. D[ Ar ] 4 s^2 3 d^4 and [ Ar ] 4 s^2 3 d^9

Correct answer

A. [ Ar ] 4 s^1 3 d^5 and [ Ar ] 4 s^1 3 d¹⁰

Step-by-step solution

Chromium and copper have five and ten electrons in 3 d -orbitals rather than four and nine because fully-filled and half-filled orbitals have lower energy and thus have extra stability. Therefore, chromium and copper have d^5 and d¹⁰ -configurations.

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