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Manipal MET2010ChemistryElectrochemistry

E^ values of Mg ²⁺ / Mg is -2.37 V , of Zn ²⁺ / Zn is -0.76 V and Fe ²⁺ / Fe is -0.44 V . Which of the statements is correct?

Options

  1. AZn will reduce Fe ²⁺
  2. BZn will reduce Mg ²⁺
  3. CMg oxidises Fe
  4. DZn oxidises Fe

Correct answer

A. Zn will reduce Fe ²⁺

Step-by-step solution

Higher the negative value of E^ , more is the reducing power. The order of E^ values (negative value) is - 2.37 ( Mg ) - 0.76 ( Zn ) - 0.44 ( Fe ) Mg can reduce both Zn ²⁺ and Fe ²⁺ . Zn can reduce Fe ²⁺ , but not Mg ²⁺ . Fe cannot reduce Mg and Zn but can oxidise them.

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