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AIIMS 2015
Exam
AIIMS
Year
2015
Subject
Chemistry
Chapter
Chemical Kinetics

AIIMS 2015 · Chemistry · Chemical Kinetics

For reaction a A arrow x P , when [A]=2.2 mM , the rate was found...

For reaction aA→xPa A \rightarrow x P, when [A]=2.2mM[A]=2.2 \mathrm{mM}, the rate was found to be 2.4mMs−12.4 \mathrm{mM} \mathrm{s}^{-1}. On reducing concentration of AA to half, the rate changes to 0.6mMs−10.6 \mathrm{mM} \mathrm{s}^{-1}. The order of reaction with respect to AA is

Options

  1. A1.5
  2. B2.0
  3. C2.5
  4. D3.0

Correct answer

B. 2.0

Step-by-step solution

aA→xPa A \rightarrow x P Rate of reaction =[A]a=[A]^a Order of reaction =a=a [A]1=2.2mM,r1=2.4mMs−1[A]_1=2.2 \mathrm{mM}, r_1=2.4 \mathrm{mM} \mathrm{s}^{-1} [A]2=2.22mM,r2=0.6[A]_2=\frac{2.2}{2} \mathrm{mM}, r_2=0.6 or 2.44mMs−1\frac{2.4}{4} \mathrm{mM} \mathrm{s}^{-1} On reducing the concentration of AA to half, the rate of reaction is decreased by four times. ∴\therefore Rate of reaction ∝[A]2\propto[A]^2 ⇒\Rightarrow Order of reaction =2=2
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