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MHT CET202620 April 2026Evening ShiftChemistryChemical KineticsActual

What is the order and molecularity of the following elementary reaction? 2 NO _ 2(g) 2 NO _ (g) + O _ 2(g) , rate = k [ NO ₂]^2

Options

  1. AThe reaction is second order and biomolecular.
  2. BThe reaction is first order and bimolecular.
  3. CThe reaction is second order and unimolecular.
  4. DThe reaction is zero order and unimolecular.

Correct answer

A. The reaction is second order and biomolecular.

Step-by-step solution

For an elementary reaction, the rate law is determined by its stoichiometry. Given rate = k[ NO ₂]^2 The order of the reaction is the sum of the exponents of the concentration terms in the rate law. Here, the exponent is 2 , so the order is 2 . The molecularity of an elementary reaction is the number of reactant molecules participating in the reaction. Since 2 molecules of NO ₂ are reacting, the molecularity is 2 (bimolecular). Thus, the reaction is second order and bimolecular. Answer: The reaction is second order

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