MHT CET202620 April 2026Morning ShiftChemistryChemical KineticsActual
Identify correct statement regarding order of reaction from following.
Options
- ARate of zero order reaction depends on initial concentration of reactant.
- BDecomposition of acetaldehyde is a first order reaction.
- CHalf life of first order reaction is independent of initial concentration of reactant.
- DHalf life of zero order reaction is independent of initial concentration of reactant
Correct answer
C. Half life of first order reaction is independent of initial concentration of reactant.
Step-by-step solution
For a zero order reaction, the rate is given by r = k[A]^0 = k . Thus, the rate is independent of the concentration of the reactant. The decomposition of acetaldehyde ( CH₃CHO CH₄ + CO ) is a fractional order reaction with an order of 1.5 . For a first order reaction, the half-life is given by t_ 1/2 = 0.693 k . This shows that the half-life is independent of the initial concentration of the reactant. For a zero order reaction, the half-life is given by t_ 1/2 = [A]₀ 2k . This shows that the half-life is directly p