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MHT CET202522 Apr 2025Morning ShiftChemistryChemical KineticsActual

Rate law for the reaction aA + bB cC + dD is r = k [ A ][ B ] , the rate of reaction doubles if

Options

  1. AConcentration of both A and B are doubled.
  2. BConcentration of A is doubled and concentration of B is kept constant.
  3. CConcentration of B is doubled and concentration of A is halved.
  4. DConcentration of A is kept constant and concentration of B is halved.

Correct answer

B. Concentration of A is doubled and concentration of B is kept constant.

Step-by-step solution

The rate law is given as r = k[A][B] for the reaction aA + bB cC + dD . The initial rate is r₁ = k[A][B] . To double the rate, we require r₂ = 2r₁ = 2k[A][B] . When concentration A is doubled while B remains constant, the new rate becomes k(2[A])([B]) = 2k[A][B] . This matches the required doubling condition, confirming option B is correct. Other options yield different results: doubling both concentrations quadruples the rate, doubling B while halving A maintains the original rate, and halving B while keeping A co

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