Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
MHT CET202522 Apr 2025Morning ShiftChemistryChemical KineticsActual

Half life of a first order reaction is 20 minute. The time taken to reduce the initial concentration of reactant to (1 / 10)^ th is

Options

  1. A46 60 ~min
  2. B66.46 min
  3. C79.68 min
  4. D88.00 min

Correct answer

B. 66.46 min

Step-by-step solution

Half-life and first-order reaction kinetics provide the framework for solving this problem. The half-life t_ 1/2 = 20 min yields the rate constant k = 0.693 t_ 1/2 = 0.03465 min ⁻¹ . The integrated rate law k = 2.303 t [A]₀ [A]_t applies when [A]_t = 1 10 [A]₀ , making [A]₀ [A]_t = 10 = 1 . Rearranging gives t = 2.303 k = 2.303 0.03465 66.46 min . The result corresponds to option B: 66.46 min .

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

When the concentration of the reactant in a given reaction is halved and if the rate of reaction is halved, the order of the reaction is: 2026A first order reaction is 50%complete in 30 minutes at 300 K and in 10 minutes at 320 K. The activation energy of the reaction (E_a ) is: [R=8.314 J K ⁻¹ mol ⁻¹ ; log 2 = 0.3010; l 2026In the synthesis of NH₃ from H₂ and N₂ , if 6 10⁻² mole of hydrogen disappears in 10 minutes, the number of moles of NH₃ formed in 0.3 minutes is: 2026The initial pressure of the system before decomposition for a first order gas phase reaction A_ (g) B_ (g) + C_ (g) was P_i . After lapse of time 't', total pressure of the system 2026Which of the following factors is altered by the addition of a catalyst during a chemical reaction? 2026The rate constants for two different reactions, k₁ and k₂ are 10¹⁶ e^ -2000/T and 10¹⁵ e^ -1000/T respectively. The temperature at which k₁ = k₂ is 202660% of a first order reaction was completed in 60 min, then 50% of the same reaction can be completed in: [log 4 = 0.60, log 5=0.69] 2026Identify the correct values to be plotted in the graph, the slope of which can be used to determine the activation energy of a reaction. 2026 Full Chemical Kinetics list All MHT CET PYQs