MHT CET202521 Apr 2025Morning ShiftChemistryChemical KineticsActual
If a reaction occurs in following two steps i) 2 ClO ⁻ ClO ₂⁻ ii) ClO ₂⁻+ ClO ⁻ ClO ₃⁻+ Cl ⁻ Find the reaction intermediate.
Options
- AClO ⁻
- BClO ₃⁻
- CCl ⁻
- DClO ₂⁻
Correct answer
D. ClO ₂⁻
Step-by-step solution
A reaction intermediate is a species formed in one elementary step and consumed in a subsequent step, not appearing in the overall balanced equation. Analyzing the given mechanism: Step i: 2 ClO ⁻ ClO ₂⁻ Step ii: ClO ₂⁻ + ClO ⁻ ClO ₃⁻ + Cl ⁻ ClO ₂⁻ is produced in step i and consumed in step ii, satisfying the definition of an intermediate. Summing the steps confirms this: 2 ClO ⁻ + ClO ₂⁻ + ClO ⁻ ClO ₂⁻ + ClO ₃⁻ + Cl ⁻ Canceling ClO ₂⁻ from both sides yields the overall equation: 3 ClO ⁻ ClO ₃⁻ + Cl ⁻ ClO ₂⁻ does n