MHT CET202520 Apr 2025Evening ShiftChemistryChemical KineticsActual
What is order and molecularity of following reaction? NO _ 2( ~g ) + NO _ 2( ~g ) 2 NO _ ( g ) + O _ 2( ~g )
Options
- Aorder 1, molecularity 2
- Border 2, molecularity 2
- Corder 2, molecularity 3
- Dorder zero, molecularity 2
Correct answer
B. order 2, molecularity 2
Step-by-step solution
Molecularity refers to the number of reacting species involved in an elementary step. In this reaction, two NO ₂ molecules collide, so the molecularity is 2. For elementary reactions, the order equals molecularity with rate law determined directly from stoichiometry. The reaction 2 NO _ 2( g ) 2 NO _ ( g ) + O _ 2( g ) implies Rate = k[ NO ₂]^2 , making the order 2. Since both order and molecularity are 2, the correct choice is B .