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MHT CET20239 May 2023Evening ShiftChemistryChemical KineticsActual

Calculate the rate constant of first order reaction if the concentration of the reactant decreases by 90 % in 30 minutes.

Options

  1. A7.7 10⁻² minute ⁻¹
  2. B4.2 10⁻² minute ⁻¹
  3. C2.1 10⁻² minute ⁻¹
  4. D3.5 10⁻² minute ⁻¹

Correct answer

A. 7.7 10⁻² minute ⁻¹

Step-by-step solution

Concentration decreases by 90 % . Hence, 10 % reactant is left after 30 minutes. aligned k & = 2.303 t ₁₀ [ A ]₀ [ ~A ]_ t k & = 2.303 30 ₁₀ 100 10 & = 2.303 30 ~min & =7.7 10⁻² ~min ⁻¹ aligned

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