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MHT CET202620 April 2026Evening ShiftChemistryCoordination CompoundsActual

Which of the following complex is neutral?

Options

  1. AK ₃[ Fe(CN) ₅ NO ]
  2. B[ Zn(NH ₃)₄]²⁺
  3. C[ Co(NH ₃)₅ Cl ]²⁺
  4. D[ Ni(CO) ₄]

Correct answer

D. [ Ni(CO) ₄]

Step-by-step solution

A neutral complex is a coordination compound that does not have an overall electrical charge and does not dissociate into ions in solution. K ₃[ Fe(CN) ₅ NO ] is an ionic complex that dissociates into 3 K ^+ and [ Fe(CN) ₅ NO ]³⁻ ions. [ Zn(NH ₃)₄]²⁺ is a cationic complex with a +2 charge. [ Co(NH ₃)₅ Cl ]²⁺ is a cationic complex with a +2 charge. [ Ni(CO) ₄] has no overall charge and no counter ions, making it a neutral complex. Answer: [ Ni(CO) ₄]

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