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MHT CET202611 April 2026Morning ShiftChemistryCoordination CompoundsActual

Identify the hybridization in central metal of [ Fe ( CO )₅] complex.

Options

  1. Adsp^3
  2. Bsp^3 d^2
  3. Cd^2 sp^3
  4. Dsp^3

Correct answer

A. dsp^3

Step-by-step solution

In [Fe(CO)₅] , the central metal atom is Fe and its oxidation state is 0 . The ground state electronic configuration of Fe is [Ar] 3d^6 4s^2 . CO is a strong field ligand, which causes the pairing of electrons. The two 4s electrons shift to the 3d subshell and pair up, resulting in a 3d^8 configuration. Four 3d orbitals are completely filled and one 3d orbital is left empty. To accommodate the five electron pairs from the five CO ligands, one 3d , one 4s , and three 4p orbitals hybridize. Therefore, the hybridizati

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