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MHT CET202523 Apr 2025Morning ShiftChemistryCoordination CompoundsActual

What is EAN of metal ion in hexacyanoferrate (II) ion?

Options

  1. A36
  2. B38
  3. C37
  4. D35

Correct answer

A. 36

Step-by-step solution

The Effective Atomic Number (EAN) for the metal ion in [ Fe ( CN )₆]⁴⁻ is determined through systematic analysis of its electronic configuration. The central metal ion is iron with atomic number Z = 26 . The oxidation state calculation yields x + 6 (-1) = -4 , resulting in x = +2 for Fe ²⁺ . The number of electrons in Fe ²⁺ is 26 - 2 = 24 . Each cyanide ligand donates 2 electrons, with 6 ligands contributing 6 2 = 12 electrons. EAN = 24 + 12 = 36 Therefore, the Effective Atomic Number is 36 .

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