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MHT CET202521 Apr 2025Evening ShiftChemistryCoordination CompoundsActual

What is the number of moles of silver chloride precipitated when excess silver nitrate is treated with one mole of pentaamminecarbonatocobalt(III) chloride?

Options

  1. A4
  2. B3
  3. C2
  4. D1

Correct answer

D. 1

Step-by-step solution

Pentaamminecarbonatocobalt(III) chloride features a Co³⁺ center coordinated to five neutral NH₃ ligands and one CO₃²⁻ ligand, giving the complex ion [ Co(NH₃)5CO3 ]^+ with charge +3 + 0 - 2 = +1 . Silver nitrate test for ionic chloride: Each formula unit contains one Cl- ion, producing one mole of AgCl precipitate per mole of compound. E = mass of AgCl molar mass of AgCl = 2.87 , g 143.32 , g/mol = 0.02 , mol Since one mole of compound yields one mole of AgCl , the moles of silver chloride precipitated are 0.02 , m

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