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MHT CET202521 Apr 2025Morning ShiftChemistryCoordination CompoundsActual

Which from following cations will form most stable complex with same ligand?

Options

  1. ACu ²⁺
  2. BCo ²⁺
  3. CMn ²⁺
  4. DFe ²⁺

Correct answer

A. Cu ²⁺

Step-by-step solution

The stability of coordination complexes formed by divalent transition metal ions follows the Irving-Williams series: Mn²⁺ Zn²⁺ . This trend results from decreasing ionic radii and increasing effective nuclear charge across the period, enhanced by crystal field stabilization effects. Among the given ions, Cu²⁺ exhibits the highest stability due to maximum crystal field stabilization energy among first-row transition metals and Jahn-Teller distortion effects. Final Answer: A

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