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MHT CET20243 May 2024Morning ShiftChemistryCoordination CompoundsActual

Identify the formula of pentaaquaisothiocyanatoiron(III) ion from following.

Options

  1. AFe [ ( H ₂ O )₅( SCN ) ]³⁺
  2. B[ Fe ( H ₂ O )₅( NCS ) ]²⁺
  3. CFe [ ( H ₂ O )₃( NCS )₂ ]³⁺
  4. D[ Fe [ ( H ₂ O )₂( SCN )₃ ]⁵⁺ .

Correct answer

B. [ Fe ( H ₂ O )₅( NCS ) ]²⁺

Step-by-step solution

Pentaaqua - This means there are five water molecules, ( ( H ₂ O )₅ ), ligated to the central metal. Isothiocyanato - This refers to the presence of one isothiocyanate ion, represented as (NCS). Iron(III) ion - This indicates that the oxidation state of iron is +3. However, because of ligands and their charges, the net charge on the complex ion should be reconciled. Thus, the stated charge in the problem is a critical clue, as this aligns with the options provided. Option B aligns with these points, providing the c

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