AIIMS 2005
- Exam
- AIIMS
- Year
- 2005
- Subject
- Chemistry
- Chapter
- Classification of Elements and Periodicity in Properties
AIIMS 2005 · Chemistry · Classification of Elements and Periodicity in Properties
Assertion : First ionization energy for nitrogen is lower than...
Assertion : First ionization energy for nitrogen is lower than oxygen.
Reason : Across a period effective nuclear charge decreases.
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion
- BIf both assertion and reason are true but reason is not the correct explanation of assertion
- CIf assertion is true but reason is false
- DIf both assertion and reason are false.
Correct answer
D. If both assertion and reason are false.
Step-by-step solution
First ionization energy for nitrogen is greater than oxygen.
This is due to stable configuration of nitrogen (halffilled -orbital).
Due to screening effect the valency electron experiences less attraction towards the nucleus. This brings decrease in the nuclear charge $(Z) actually present on the nucleus. The reduced nuclear charge is termed effective nuclear charge and its magnitude increases in a period when we move from left to right.