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AIIMS 2005
Exam
AIIMS
Year
2005
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

AIIMS 2005 · Chemistry · Classification of Elements and Periodicity in Properties

Assertion : First ionization energy for nitrogen is lower than...

Assertion : First ionization energy for nitrogen is lower than oxygen. Reason : Across a period effective nuclear charge decreases.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

D. If both assertion and reason are false.

Step-by-step solution

First ionization energy for nitrogen is greater than oxygen. NOeV14.513.6\begin{array}{ccc}& \mathrm{N}& \mathrm{O}\\ \mathrm{eV}& 14.5 & 13.6 \end{array}This is due to stable configuration of nitrogen (halffilled 2p2 p-orbital). Due to screening effect the valency electron experiences less attraction towards the nucleus. This brings decrease in the nuclear charge $(Z) actually present on the nucleus. The reduced nuclear charge is termed effective nuclear charge and its magnitude increases in a period when we move from left to right.
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