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MHT CET202013 Oct 2020Evening ShiftChemistryCoordination CompoundsActual

Which among the following complexes is a homoleptic and cationic in nature?

Options

  1. A[ CoCl ₂( en )₂ ] Cl
  2. B[ Fe ( H ₂ O )₆ ] Cl ₃
  3. CK [ Ag ( CN )₂ ]
  4. D[ F _ e ( CO )₅ ]

Correct answer

B. [ Fe ( H ₂ O )₆ ] Cl ₃

Step-by-step solution

[ Fe ( H ₂ O )₆ ] Cl ₃ [ Fe ( H ₂ O )₆ ]³⁺+3 Cl ⁻ i. Homoleptic - Fe is linked to only one type of ligand, H ₂ O . ii. Cationic Complex - due to positive charge on complex ion.

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