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MHT CET202613 April 2026Evening ShiftChemistryd and f Block ElementsActual

Which of the following cations in their oxidation states forms colored compounds ?

Options

  1. ASc ³⁺
  2. BTi ⁴⁺
  3. CCu ^+
  4. DV ³⁺

Correct answer

D. V ³⁺

Step-by-step solution

The electronic configurations of the given cations are: Sc ³⁺ ( Z=21 ): [ Ar ] 3d^0 Ti ⁴⁺ ( Z=22 ): [ Ar ] 3d^0 Cu ⁺ ( Z=29 ): [ Ar ] 3d¹⁰ V ³⁺ ( Z=23 ): [ Ar ] 3d^2 Cations with d^0 or d¹⁰ configurations do not have unpaired electrons for d-d transitions and are generally colorless. V ³⁺ has two unpaired electrons in its d -orbital, which allows d-d transitions, making its compounds colored. Answer: V ³⁺

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