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MHT CET202525 Apr 2025Evening ShiftChemistryd and f Block ElementsActual

Which from following elements in respective oxidation state develops highest spin only magnetic moment?

Options

  1. AMn ²⁺
  2. BTi ³⁺
  3. CCu ²⁺
  4. DNi ²⁺

Correct answer

A. Mn ²⁺

Step-by-step solution

The spin-only magnetic moment is determined by = n(n+2) BM, where n is the number of unpaired electrons. Electronic configurations and unpaired electron counts are analyzed for each ion. Mn ²⁺ has configuration [ Ar ] 3d^5 with n = 5 , yielding = 35 5.92 BM. Ti ³⁺ is [ Ar ] 3d^1 , n = 1 , = 3 1.73 BM. Cu ²⁺ is [ Ar ] 3d^9 , n = 1 , = 3 1.73 BM. Ni ²⁺ is [ Ar ] 3d^8 , n = 2 , = 8 2.83 BM. Mn ²⁺ exhibits the highest magnetic moment.

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