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MHT CET202521 Apr 2025Evening ShiftChemistryd and f Block ElementsActual

Which form following elements forms coloured compound in its respective oxidation state?

Options

  1. ASc ³⁺
  2. BTi ⁴⁺
  3. CZn ²⁺
  4. DCr ³⁺

Correct answer

D. Cr ³⁺

Step-by-step solution

Transition metal ions form colored compounds when they possess partially filled d-orbitals with unpaired electrons, enabling d-d transitions that absorb visible light. Analyzing the electronic configurations: Sc ³⁺ has configuration [ Ar ] 3d^0 , Zn ²⁺ has [ Ar ] 3d¹⁰ , and Ti ⁴⁺ has [ Ar ] 3d^0 – all lack the necessary unpaired d-electrons for d-d transitions. Cr ³⁺ has configuration [ Ar ] 3d^3 with three unpaired electrons, allowing d-d transitions that produce colored compounds such as the characteristic green

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