MHT CET202616 April 2026Evening ShiftChemistryElectrochemistryActual
Which of the following reactions takes place at anode during the electrolysis of molten NaCl?
Options
- ANa ^+_ (l) + e ^- Na _ (l)
- BNa _ (s) Na ^+_ (l) + e ^-
- CCl _ 2(g) + 2 e ^- 2 Cl ^-_ (l)
- D2 Cl ^-_ (l) Cl _ 2(g) + 2 e ^-
Correct answer
D. 2 Cl ^-_ (l) Cl _ 2(g) + 2 e ^-
Step-by-step solution
During the electrolysis of molten NaCl , the ions present are Na ^+ and Cl ^- . At the anode, oxidation takes place. The chloride ions ( Cl ^- ) migrate to the anode and lose electrons to form chlorine gas. The reaction at the anode is: 2 Cl ^-_ (l) Cl _ 2(g) + 2 e ^- At the cathode, reduction takes place. The sodium ions ( Na ^+ ) migrate to the cathode and gain electrons to form liquid sodium. The reaction at the cathode is: Na ^+_ (l) + e ^- Na _ (l) Answer: 2 Cl ^-_ (l) Cl _ 2(g) + 2 e ^-