MHT CET202523 Apr 2025Evening ShiftChemistryElectrochemistryActual
A hypothetical galvanic cell is _ A _ ( s ) | A ⁺(1 M ) | | B ⁺²(1 M ) | B _ ( s ) ^ and emf of cell is positive. What is the possible cell reaction?
Options
- AA _ ( s ) + B _ ( aq ) ⁺² ~A _ ( aq ) ⁺¹+ B _ ( s )
- B2 ~A _ ( s ) + B _ ( aq ) ⁺² 2 + A _ ( aq ) ¹+ B _ ( s )
- CA _ ( s ) +2 ~B _ ( aq ) ⁺² ~A _ ( aq ) ⁺¹+2 ~B _ ( s )
- D2 ~A _ ( aq ) ⁺+ B _ ( s ) 2 ~A _ ( s ) + +2 ~B _ ( aq )
Correct answer
B. 2 ~A _ ( s ) + B _ ( aq ) ⁺² 2 + A _ ( aq ) ¹+ B _ ( s )
Step-by-step solution
Cell notation: _ A _ ( s ) | A ⁺(1 M )|| B ⁺²(1 M )| B _ ( s ) ^ The anode (left side) shows oxidation of A to A ⁺ , while the cathode (right side) shows reduction of B ²⁺ to B . The oxidation half-reaction is A _ ( s ) A ⁺_ ( aq ) + e ⁻ , and the reduction half-reaction is B ²⁺_ ( aq ) + 2 e ⁻ B _ ( s ) . To balance electrons, multiply the oxidation half-reaction by 2: 2 A _ ( s ) 2 A ⁺_ ( aq ) + 2 e ⁻ . Combining both half-reactions gives 2 A _ ( s ) + B ²⁺_ ( aq ) 2 A ⁺_ ( aq ) + B _ ( s ) , which matches option