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MHT CET202522 Apr 2025Morning ShiftChemistryElectrochemistryActual

Which of the following reactions exhibit minimum standard reduction potential?

Options

  1. A2 H _ ( aq ) ⁺+2 e H _ 2( ~g )
  2. BF _ 2( ~g ) +2 e 2 ~F _ ( aq ) ⁻
  3. CLi _ ( aq ) ⁺+ e Li _ ( s )
  4. DCl _ 2( ~g ) +2 e 2 Cl _ ( aq ) ⁻

Correct answer

C. Li _ ( aq ) ⁺+ e Li _ ( s )

Step-by-step solution

The standard reduction potential E^ is a measure of the tendency for a species to gain electrons. Comparing the given reactions: For the standard hydrogen electrode, 2 H ⁺_ ( aq ) + 2 e ^- H _ 2( g ) , E^ = 0.00~ V . F _ 2( g ) + 2 e ^- 2 F ⁻_ ( aq ) has E^ = +2.87~ V . Li ⁺_ ( aq ) + e ^- Li _ ( s ) exhibits the most negative value, E^ = -3.05~ V . Cl _ 2( g ) + 2 e ^- 2 Cl ⁻_ ( aq ) has E^ = +1.36~ V . The minimum standard reduction potential corresponds to the lithium reduction reaction. Final answer: C

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