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MHT CET202521 Apr 2025Morning ShiftChemistryElectrochemistryActual

If E ^ ( Mg ⁺² _ ( aq ) Mg _ ( s ) )=-2.37 ~V . What is potential for Mg _ ( s ) Mg ⁺²(0.1 M )+2 e at 298 K ?

Options

  1. A+2.3996 ~V
  2. B-2.3996 ~V
  3. C+2.3404 ~V
  4. D-2.3404 ~V

Correct answer

A. +2.3996 ~V

Step-by-step solution

The standard oxidation potential E^ _ ox is determined from the given reduction potential E^ ( Mg ⁺²_ ( aq ) Mg _ ( s ) ) = -2.37 , V : E^ _ ox = -E^ _ red = +2.37 , V For the reaction Mg _ ( s ) Mg ⁺²(0.1 , M ) + 2e^- , the number of electrons transferred is n = 2 and the reaction quotient is Q = [ Mg ⁺²] = 0.1 . The Nernst equation gives the oxidation potential as: E = E^ _ ox - 0.0592 n Q = 2.37 - 0.0592 2 (0.1) Since (0.1) = -1 , the calculation becomes: E = 2.37 - 0.0296 (-1) = 2.37 + 0.0296 = 2.3996 , V Final

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