MHT CET202525 Apr 2025Evening ShiftChemistrys Block ElementsActual
Which colour is developed to the solution when alkaline earth metals are dissolved in liquid ammonia ?
Options
- ACrimson red
- BDeep blue black
- COrange
- DFaint green
Correct answer
B. Deep blue black
Step-by-step solution
Alkaline earth metals dissolved in liquid ammonia , analogous to alkali metals, ionize to form metal cations and free electrons, which then solvate with ammonia molecules as ammoniated electrons . These electrons are responsible for the deep blue coloration, high conductivity, and paramagnetic behavior of the solution. At higher concentrations, the solution transitions to a bronze appearance and diamagnetic character due to electron association. M(s) + (x+y)NH₃(l) [M(NH₃)_x]²⁺(am) + 2[e(NH₃)_y]^-(am) Ammoniated ele