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MHT CET2016Chemistrys Block Elements

Which halide of magnesium has the highest ionic character?

Options

  1. AChloride
  2. BBromide
  3. CIodide
  4. DFluoride

Correct answer

D. Fluoride

Step-by-step solution

Size of anion is I − > B r − > C l − > F − . As the size increases, polarisation of an anion is more, hence when covalent character increases ionic character decreases. Order of ionic character is M g F 2 > M g C l 2 > M g B r 2 > M g I 2 Hence Magnesium fluoride has the highest ionic character.

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