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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

If the shortest wavelength of the Lyman series for a hydrogen atom...

If the shortest wavelength of the Lyman series for a hydrogen atom is xx, then the longest wavelength of the Paschen series for a He+\mathrm{He}^{+} ion is:

Options

  1. A7x36\dfrac{7x}{36}
  2. B144x7\dfrac{144x}{7}
  3. C36x7\dfrac{36x}{7}
  4. D9x4\dfrac{9x}{4}

Correct answer

C. 36x7\dfrac{36x}{7}

Step-by-step solution

The Rydberg formula for the wavelength of emitted radiation is given by:

1λ=RZ2(1n12−1n22)\dfrac{1}{\lambda} = R Z^2 \left( \dfrac{1}{n_1^2} - \dfrac{1}{n_2^2} \right)

For the shortest wavelength of the Lyman series for a hydrogen atom, Z=1Z = 1, n1=1n_1 = 1, and n2=∞n_2 = \infty. Substituting these values:

1x=R(1)2(112−1∞)=R\dfrac{1}{x} = R (1)^2 \left( \dfrac{1}{1^2} - \dfrac{1}{\infty} \right) = R

For the longest wavelength of the Paschen series for a He+\mathrm{He}^{+} ion, Z=2Z = 2, n1=3n_1 = 3, and n2=4n_2 = 4. Let this wavelength be λ\lambda. Substituting these values:

1λ=R(2)2(132−142)\dfrac{1}{\lambda} = R (2)^2 \left( \dfrac{1}{3^2} - \dfrac{1}{4^2} \right)

1λ=4R(19−116)\dfrac{1}{\lambda} = 4R \left( \dfrac{1}{9} - \dfrac{1}{16} \right)

1λ=4R(16−9144)=4R(7144)=7R36\dfrac{1}{\lambda} = 4R \left( \dfrac{16 - 9}{144} \right) = 4R \left( \dfrac{7}{144} \right) = \dfrac{7R}{36}

Substituting R=1xR = \dfrac{1}{x} into the equation:

1λ=736x\dfrac{1}{\lambda} = \dfrac{7}{36x}

λ=36x7\lambda = \dfrac{36x}{7}

Answer: 36x7\dfrac{36x}{7}
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