NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Consider the following sequences of molecules and their associated...
Consider the following sequences of molecules and their associated properties:
(I) : Dipole moment
(II) : Bond angle
(III) : bond length
(IV) : Bond order
Which of the above sequences are correct?
(I) : Dipole moment
(II) : Bond angle
(III) : bond length
(IV) : Bond order
Which of the above sequences are correct?
Options
- AI and IV only
- BII and III only
- CI and II only
- DIII and IV only
Correct answer
A. I and IV only
Step-by-step solution
Statement (I): The dipole moment of chloromethanes decreases as the number of chlorine atoms increases due to the vector addition of individual bond moments. The experimental values are ( D) ( D) ( D). This sequence is correct.
Statement (II): The bond angle of group 16 hydrides decreases down the group. As the electronegativity of the central atom decreases, the bond pairs move further away from the central atom, decreasing the bond pair-bond pair repulsion. The correct order is () () (). This sequence is incorrect.
Statement (III): The bond order of is , is , and is . Since bond length is inversely proportional to bond order, the correct order of bond length is . This sequence is incorrect.
Statement (IV): The total number of electrons in , , and are , , and respectively. According to molecular orbital theory, their bond orders are , , and respectively. The correct order of bond order is . This sequence is correct.
Therefore, only sequences I and IV are correct.
Answer: I and IV only
Statement (II): The bond angle of group 16 hydrides decreases down the group. As the electronegativity of the central atom decreases, the bond pairs move further away from the central atom, decreasing the bond pair-bond pair repulsion. The correct order is () () (). This sequence is incorrect.
Statement (III): The bond order of is , is , and is . Since bond length is inversely proportional to bond order, the correct order of bond length is . This sequence is incorrect.
Statement (IV): The total number of electrons in , , and are , , and respectively. According to molecular orbital theory, their bond orders are , , and respectively. The correct order of bond order is . This sequence is correct.
Therefore, only sequences I and IV are correct.
Answer: I and IV only