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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Consider the following sequences of molecules and their associated...

Consider the following sequences of molecules and their associated properties:

(I) CH3Cl>CH2Cl2>CHCl3\mathrm{CH}_3\mathrm{Cl} \gt \mathrm{CH}_2\mathrm{Cl}_2 \gt \mathrm{CHCl}_3 : Dipole moment
(II) H2Te>H2S>H2O\mathrm{H}_2\mathrm{Te} \gt \mathrm{H}_2\mathrm{S} \gt \mathrm{H}_2\mathrm{O} : Bond angle
(III) CO>CO2>CO32−\mathrm{CO} \gt \mathrm{CO}_2 \gt \mathrm{CO}_3^{2-} : C−O\mathrm{C}-\mathrm{O} bond length
(IV) NO+>NO>NO−\mathrm{NO}^+ \gt \mathrm{NO} \gt \mathrm{NO}^- : Bond order

Which of the above sequences are correct?

Options

  1. AI and IV only
  2. BII and III only
  3. CI and II only
  4. DIII and IV only

Correct answer

A. I and IV only

Step-by-step solution

Statement (I): The dipole moment of chloromethanes decreases as the number of chlorine atoms increases due to the vector addition of individual bond moments. The experimental values are CH3Cl\mathrm{CH}_3\mathrm{Cl} (1.871.87 D) >\gt CH2Cl2\mathrm{CH}_2\mathrm{Cl}_2 (1.601.60 D) >\gt CHCl3\mathrm{CHCl}_3 (1.041.04 D). This sequence is correct.

Statement (II): The bond angle of group 16 hydrides decreases down the group. As the electronegativity of the central atom decreases, the bond pairs move further away from the central atom, decreasing the bond pair-bond pair repulsion. The correct order is H2O\mathrm{H}_2\mathrm{O} (104.5∘104.5^\circ) >\gt H2S\mathrm{H}_2\mathrm{S} (92.1∘92.1^\circ) >\gt H2Te\mathrm{H}_2\mathrm{Te} (90∘90^\circ). This sequence is incorrect.

Statement (III): The bond order of CO\mathrm{CO} is 33, CO2\mathrm{CO}_2 is 22, and CO32−\mathrm{CO}_3^{2-} is 1.331.33. Since bond length is inversely proportional to bond order, the correct order of C−O\mathrm{C}-\mathrm{O} bond length is CO32−>CO2>CO\mathrm{CO}_3^{2-} \gt \mathrm{CO}_2 \gt \mathrm{CO}. This sequence is incorrect.

Statement (IV): The total number of electrons in NO+\mathrm{NO}^+, NO\mathrm{NO}, and NO−\mathrm{NO}^- are 1414, 1515, and 1616 respectively. According to molecular orbital theory, their bond orders are 33, 2.52.5, and 22 respectively. The correct order of bond order is NO+>NO>NO−\mathrm{NO}^+ \gt \mathrm{NO} \gt \mathrm{NO}^-. This sequence is correct.

Therefore, only sequences I and IV are correct.

Answer: I and IV only
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