Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryRedox Reactions

Which of the following species cannot undergo a disproportionation reaction?

Options

  1. AHNO ₂
  2. BH ₂ O ₂
  3. CHClO ₄
  4. DBr ₂

Correct answer

C. HClO ₄

Step-by-step solution

For a species to undergo disproportionation, the element must be present in an intermediate oxidation state so that it can be both oxidized (increase in oxidation state) and reduced (decrease in oxidation state). In HClO ₄ , the oxidation state of chlorine is +7 , which is its maximum possible oxidation state for the element. Therefore, it can only undergo reduction and cannot be oxidized further. Hence, HClO ₄ cannot undergo disproportionation. In HNO ₂ , N is in the +3 state and can disproportionate to +5 and +2

Practice Redox Reactions on Quantrex Academy →

More from Redox Reactions

500 mL of 0.2 M MnO₄^- solution in basic medium when mixed with 500 mL of 1.5 M KI solution, oxidises iodide ions to liberate molecular iodine. This liberated iodine is then titrat 2026Given below are two statements: Statement I: Sodium dichromate and potassium dichromate are classified as primary standards in titrimetric analysis. Statement II: Phenolphthalein i 2026In order to oxidise a mixture of 1 mole each of FeC₂O₄ , Fe₂(C₂O₄)₃ , FeSO₄ and Fe₂(SO₄)₃ in acidic medium, the number of moles of KMnO₄ required is 2026500 mL of 1.2 M KI solution is mixed with 500 mL of 0.2 M KMnO ₄ solution in basic medium. The liberated iodine was titrated with standard 0.1 M Na ₂ ~S ₂ O ₃ solution in the prese 2026One mole of Cl ₂( ~g ) was passed into 2 L of cold 2 M KOH solution. After the reaction, the concentrations of Cl ⁻, ClO ⁻ and OH ⁻ are respectively (assume volume remains constant 2026X and Y are the number of electrons involved, respectively during the oxidation of I ⁻ to I ₂ and S ²⁻ to S by acidified K ₂ Cr ₂ O ₇ . The value of X + Y is _ _ _ _ . 2026200 cc of x 10⁻³ M potassium dichromate is required to oxidise 750 cc of 0.6 M Mohr's salt solution in acidic medium. Here x= _ _ _ _ . 2026Identify the correct statements : A. Hydrated salts can be used as primary standard. B. Primary standard should not undergo any reaction with air. C. Reactions of primary standard 2026 Full Redox Reactions list All JEE Main PYQs