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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Haloalkanes and Haloarenes

Which order of kinetics is followed by the reaction between...

Which order of kinetics is followed by the reaction between tert-butyl bromide and hydroxide ion to give tert-Butyl alcohol?

Options

  1. AZero-order kinetics.
  2. BFirst-order kinetics.
  3. CSecond-order kinetics.
  4. DThird-order kinetics.

Correct answer

B. First-order kinetics.

Step-by-step solution

The reaction between tert-butyl bromide (a tertiary alkyl halide) and hydroxide ion to form tert-butyl alcohol proceeds via the SN1S_{N}1 mechanism.

In the SN1S_{N}1 mechanism, the reaction occurs in two steps. The first step is the slow, rate-determining step, which involves the ionization of the alkyl halide to form a carbocation.

Rate = k[tert-butyl bromide]k[\text{tert-butyl bromide}]

Since the rate of the reaction depends only on the concentration of tert-butyl bromide and is independent of the concentration of the hydroxide ion, it follows first-order kinetics.

Answer: First-order kinetics.
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