MHT CET 202625 AprilEvening Shift
- Exam
- MHT CET
- Year
- 2026
- Date
- 25 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Haloalkanes and Haloarenes
MHT CET 2026 · 25 April · Evening Shift · Chemistry · Haloalkanes and Haloarenes
Which order of kinetics is followed by the reaction between...
Which order of kinetics is followed by the reaction between tert-butyl bromide and hydroxide ion to give tert-Butyl alcohol?
Options
- AZero-order kinetics.
- BFirst-order kinetics.
- CSecond-order kinetics.
- DThird-order kinetics.
Correct answer
B. First-order kinetics.
Step-by-step solution
The reaction between tert-butyl bromide (a tertiary alkyl halide) and hydroxide ion to form tert-butyl alcohol proceeds via the mechanism.
In the mechanism, the reaction occurs in two steps. The first step is the slow, rate-determining step, which involves the ionization of the alkyl halide to form a carbocation.
Rate =
Since the rate of the reaction depends only on the concentration of tert-butyl bromide and is independent of the concentration of the hydroxide ion, it follows first-order kinetics.
Answer: First-order kinetics.
In the mechanism, the reaction occurs in two steps. The first step is the slow, rate-determining step, which involves the ionization of the alkyl halide to form a carbocation.
Rate =
Since the rate of the reaction depends only on the concentration of tert-butyl bromide and is independent of the concentration of the hydroxide ion, it follows first-order kinetics.
Answer: First-order kinetics.