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MHT CET 202623 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
23 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

MHT CET 2026 · 23 April · Morning Shift · Chemistry · Ionic Equilibrium

The solubility product of Ag_2CrO_4 is 4 × 10^ -12 . What is the...

The solubility product of Ag2CrO4\text{Ag}_2\text{CrO}_4 is 4×10−124 \times 10^{-12}. What is the amount of Ag2CrO4\text{Ag}_2\text{CrO}_4 in gram present in 100100 ml its saturated solution? (molar mass of Ag2CrO4=331.73\text{Ag}_2\text{CrO}_4 = 331.73 g/mol).

Options

  1. A3.3173×10−23.3173 \times 10^{-2} g
  2. B3.3173×10−33.3173 \times 10^{-3} g
  3. C3.3173×10−43.3173 \times 10^{-4} g
  4. D3.3173×10−53.3173 \times 10^{-5} g

Correct answer

B. 3.3173×10−33.3173 \times 10^{-3} g

Step-by-step solution

Let the solubility of Ag2CrO4\text{Ag}_2\text{CrO}_4 be ss mol/L.

The dissociation reaction is:
Ag2CrO4⇌2Ag++CrO42−\text{Ag}_2\text{CrO}_4 \rightleftharpoons 2\text{Ag}^+ + \text{CrO}_4^{2-}

The solubility product KspK_{sp} is given by:
Ksp=[Ag+]2[CrO42−]=(2s)2(s)=4s3K_{sp} = [\text{Ag}^+]^2 [\text{CrO}_4^{2-}] = (2s)^2(s) = 4s^3

Given Ksp=4×10−12K_{sp} = 4 \times 10^{-12}, we have:
4s3=4×10−124s^3 = 4 \times 10^{-12}
s3=10−12s^3 = 10^{-12}
s=10−4s = 10^{-4} mol/L

The number of moles of Ag2CrO4\text{Ag}_2\text{CrO}_4 in 100100 ml (0.1L)ofsaturatedsolutionis:<br>MolesL) of saturated solution is:<br>Moles= s \times V = 10^{-4} \times 0.1 = 10^{-5}mol<br><br>TheamountofAg2CrO4mol<br><br>The amount of \text{Ag}_2\text{CrO}_4 in grams is:
Mass =Moles×Molar mass= \text{Moles} \times \text{Molar mass}
Mass =10−5×331.73=3.3173×10−3= 10^{-5} \times 331.73 = 3.3173 \times 10^{-3} g

Answer: 3.3173×10−33.3173 \times 10^{-3} g
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