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MHT CET 202622 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
22 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

MHT CET 2026 · 22 April · Evening Shift · Chemistry · Ionic Equilibrium

What is the pH of buffer solution containing 10 times higher molar...

What is the pH of buffer solution containing 1010 times higher molar concentration of weak base than the molar concentration of salt of weak base with strong acid at 298298 K? (K_bofweakbaseof weak base= 10^{-5}))

Options

  1. A66
  2. B44
  3. C99
  4. D1010

Correct answer

D. 1010

Step-by-step solution

Using the Henderson-Hasselbalch equation for a basic buffer:

pOH=pKb+log⁡([Salt][Base])<br><br>GivenpOH = pK_b + \log \left( \dfrac{[Salt]}{[Base]} \right)<br><br>Given K_b = 10^{-5},wehave, we havepK_b = -log⁡\log(10^{-5}) = 5.<br><br>Itisgiventhattheconcentrationoftheweakbaseis10.<br><br>It is given that the concentration of the weak base is 10 times the concentration of the salt, so [Base]=10[Salt][Base] = 10 [Salt], which gives [Salt][Base]=110\dfrac{[Salt]}{[Base]} = \dfrac{1}{10}.

Substituting these values into the equation:

pOH=5+log⁡(110)pOH = 5 + \log \left( \dfrac{1}{10} \right)

pOH=5−1=4pOH = 5 - 1 = 4

At 298298 K, the relationship between pH and pOH is:

pH+pOH=14pH + pOH = 14

pH=14−4=10pH = 14 - 4 = 10

Answer: 1010
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