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MHT CET 202626 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
26 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Solid State

MHT CET 2026 · 26 April · Morning Shift · Chemistry · Solid State

What is the packing efficiency of a metal crystal if it...

What is the packing efficiency of a metal crystal if it crystallizes in a face centered cubic lattice ?

Options

  1. A52.4%52.4\%
  2. B68.0%68.0\%
  3. C74.0%74.0\%
  4. D60.0%60.0\%

Correct answer

C. 74.0%74.0\%

Step-by-step solution

For a face-centered cubic (fcc) lattice, the atoms touch each other along the face diagonal of the unit cell.

Let the edge length of the unit cell be aa and the radius of each atom be rr.

The length of the face diagonal is 2a\sqrt{2}a.

Since the atoms touch along the face diagonal, we have 2a=4r\sqrt{2}a = 4r, which gives a=22ra = 2\sqrt{2}r.

The number of atoms per unit cell in an fcc lattice is Z=4Z = 4.

The volume occupied by the atoms is 4×43πr3=163πr34 \times \dfrac{4}{3}\pi r^3 = \dfrac{16}{3}\pi r^3.

The total volume of the unit cell is a3=(22r)3=162r3a^3 = (2\sqrt{2}r)^3 = 16\sqrt{2}r^3.

Packing efficiency = Volume occupied by atomsVolume of unit cell×100\dfrac{\text{Volume occupied by atoms}}{\text{Volume of unit cell}} \times 100

Packing efficiency = 163πr3162r3×100\dfrac{\dfrac{16}{3}\pi r^3}{16\sqrt{2}r^3} \times 100

Packing efficiency = π32×100\dfrac{\pi}{3\sqrt{2}} \times 100

Substituting the values of π\pi and 2\sqrt{2}, we get 3.143×1.414×100=74.0%\dfrac{3.14}{3 \times 1.414} \times 100 = 74.0\%

Answer: 74.0%74.0\%
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