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NEET Solid State PYQs with Solutions

659 previous year questions from Solid State (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

659 questionsChemistry2001–2026Answers + solutions

About Solid State PYQs

Solid State has 659 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (123), AIIMS (42), MHT CET Medical (33) and 1 other source, spanning 2001 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 33
  • 2023: 4
  • 2022: 4
  • 2021: 2
  • 2020: 2
  • 2019: 11
  • 2018: 7
  • 2017: 5
  • 2016: 5
  • 2015: 9
  • 2014: 4
  • 2013: 5

Solid State questions with solutions

1

Which of the following formulae is used to find total volume of atoms present in face-centred cubic unit cell?

MHT CET Medical 2026 Solution
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2

What is the packing efficiency of a metal crystal if it crystallizes in a face centered cubic lattice ?

MHT CET Medical 2026 Solution
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3

What is the total number of tetrahedral voids present in a single fcc unit cell?

MHT CET Medical 2026 Solution
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4

The unit cell of metal contains four particles. Calculate the volume of the unit cell if the molar mass of metal is 192\ g mol^ -1 . [ ρ × N_A = 1.5 × 10^ 25 \ g cm^ -3 mol^ -1 ]

MHT CET Medical 2026 Solution
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5

A metal forms fcc unit cell with unit edge length 400\ pm . Calculate the number of atoms present in 0.6\ g of metal if the density of metal is 12.0\ g/cm^3

MHT CET Medical 2026 Solution
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6

A compound is formed by two elements X and Y. The atoms of element Y form a hcp structure. The atoms of element X occupy 1/3 of octahedral voids. What is the formula of a compound?

MHT CET Medical 2026 Solution
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7

An element has bcc structure with atomic radius 200 pm. Find the volume of unit cell.

MHT CET Medical 2026 Solution
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8

Which of the following crystal system has four types of unit cells?

MHT CET Medical 2026 Solution
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9

What is the packing efficiency and number of atoms per unit cell present in a face centered cubic system?

MHT CET Medical 2026 Solution
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10

What is the packing efficiency in BCC unit cell ?

MHT CET Medical 2026 Solution
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11

The volume of fcc unit cell is 5.6×10^ -23 \ cm^3 . Calculate the molar mass of metal if the density of metal is 20.4\ g cm^ -3 . [N_A=6.022×10^ 23 ]

MHT CET Medical 2026 Solution
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12

Which of the following crystals are the hardest and most incompressible of all materials.

MHT CET Medical 2026 Solution
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13

In a compound, atoms of element Y form hexagonal close-packed structure. Atoms of element X occupy 2/3 of the octahedral voids. What is the formula of the compound?

MHT CET Medical 2026 Solution
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14

The density of iridium is 22.4 g cm^ -3 . The unit cell of iridium is fcc Calculate the volume of unit cell. if the molar mass of iridium is 192.2 g/mol.

MHT CET Medical 2026 Solution
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15

Match List I with List II List I (Crystalline Solids) List II (Examples) (A). Ionic Solid (I). CO_2 (B). Covalent Solid (II). K_2SO_4 (C). Molecular Solid (III). K (D). Metallic

MHT CET Medical 2026 Solution
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16

Which of the following exhibits non-stoichiometric metal deficiency?

MHT CET Medical 2026 Solution
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17

Which of the following defects exhibit colour to solid alkali metal halides?

MHT CET Medical 2026 Solution
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18

What type of the following defect is produced when NaCl crystal is doped with MgCl_2 ?

MHT CET Medical 2026 Solution
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19

Sodium forms bcc structure. The molar mass of sodium is 23 g/mol. What is the mass of 3 unit cells of sodium?

MHT CET Medical 2026 Solution
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20

Which of the following ionic crystals exhibits Schottky defect?

MHT CET Medical 2026 Solution
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21

Which one of the following elements when doped with silicon makes it p-type semiconductor ?

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22

A solid is formed of two different elements, A and B. In this atoms of A are arranged in the CCP array, and atoms of B occupy all octahedral voids and half of tetrahedral voids.

MHT CET Medical 2026 Solution
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23

Elements A and B combine to form the ionic compound A_xB_y . The anions of B are arranged in hcp array and the cations of A occupy all the octahedral voids. Determine the values

MHT CET Medical 2026 Solution
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24

If the volume of fcc unit cell is 6.4 × 10^ -23 cm^3 find the radius of an atom in it.

MHT CET Medical 2026 Solution
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25

What type of solid is the diamond?

MHT CET Medical 2026 Solution
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26

Calculate the atomic radius of an element having edge length 3.61 × 10^ -8 \ cm for fcc structure.

MHT CET Medical 2026 Solution
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27

If the edge length of a bcc unit cell is 300\ pm . Calculate the body diagonal.

MHT CET Medical 2026 Solution
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28

Which of the following information is given by XRD technique?

MHT CET Medical 2026 Solution
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29

A metal crystallizes in FCC crystal lattice with density 10 g/cm^3 . The edge length of unit cell is 100 pm. The number of unit cell present in 100 g of metal is-

MHT CET Medical 2026 Solution
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30

The silicon doped with gallium forms

MHT CET Medical 2026 Solution
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31

Which of the following crystal systems has the lowest number of Bravais lattices?

MHT CET Medical 2026 Solution
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32

Identify from following crystal system that its unit cell possesess edge length a = b = c and angle between these axes α = β = γ = 90^ ^ ∘ .

MHT CET Medical 2026 Solution
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33

Potassium forms bcc unit cell structure with edge length of 522 pm. Find the radius of the potassium atom ?

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34

How are edge length 'a' of the unit cell and radius ' r ' of the sphere related to each other in ccp structure? (Choose correct option for your answer.)

NEET 2023 Solution
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35

A compound is formed by two elements A and B. The element B forms cubic close packed structure and atoms of A occupy (1)/(3) of tetrahedral voids. If the formula of the compound

NEET 2023 Solution
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36

What fraction of one edge centred octahedral void lies in one unit cell of fcc?

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37

How many number of tetrahedral voids are formed in 5 ~mol of a compound having cubic close packed structure? (Choose the correct option)

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38

Match List-I with List-II : List-I (Defects) List-II (Shown by) (a) Frenkel defect (i) non-ionic solids and density of the solid decreases (b) Schottky defect (ii) non-ionic

NEET 2022 Solution
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39

What fraction of Fe exists as Fe (III) in Fe_ 0.96 O ? (Consider Fe_ 0.96 to be made up of Fe (II) and Fe (III) only)

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40

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R) . Assertion (A) : In a particular point defect, an ionic solid is

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41

Copper crystallizes in an FCC unit cell with cell edge of 3 .608 × 10 ^ - 8 cm . The density of copper is 8 . 92g / cm ^ 3 , Calculate the atomic mass of copper.

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42

Right option for the number of tetrahedral and octahedral voids in hexagonal primitive unit cell are:

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43

The correct option for the number of body centred unit cells in all 14 types of Bravais lattice unit cells is:

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44

An element has a body centered cubic (bcc) structure with a cell edge of 288pm . The atomic radius is

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45

Which one of the following compounds shows both, Frenkel as well as Schottky defects?

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46

The number of tetrahedral voids present in 0.5 mole of h c p crystal structure are

AIIMS 2019 Solution
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47

In f c c , distance between the nearest tetrahedral voids is

AIIMS 2019 Solution
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48

An element germanium crystallises in b c c type crystal structure with edge of unit cell equal to 288 pm and the density of the element equal to 7.2 ~g ~cm^ -3 . The number of

AIIMS 2019 Solution
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49

Assertion: ZnO becomes yellow when it is heated. Reason : Metal excess defect arises due to excess of Zn^ 2+ ions which move to interstitial sites and the electron moves to

AIIMS 2019 Solution
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50

Assertion : Ferromagnetic compound is more attracted towards magnetic field. Reason : Because all electrons are aligned in same direction.

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51

Formula of metal oxide with metal deficiency defect in its crystal is A_ 0.8 O . The crystal contains A^ 2+ and A^ 3+ ions. The fraction of metal existing as A^ 2+ ions in the

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52

Which type of defect present in NaCl ?

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53

Silicon carbide is example of

JIPMER 2019 Solution
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54

Frenkel defect is present in which of the following?

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55

A compound is formed by cation C and anion A . The anions form hexagonal close packed (hcp) lattice and the cations occupy 75% of octahedral voids. The formula of the compound is:

NEET 2019 Solution
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56

Formula of nickel oxide with metal deficiency defect in its crystal is Ni_ 0.98 O . The crystal contains Ni^ 2+ and Ni^ 3+ ions. The fraction of nickel existing as Ni^ 2+ ions in

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57

Assertion : Metal deficiency defect can be seen in FeO . Reason : Li compound ( LiCl) has pink colour due to F-center.

AIIMS 2018 Solution
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58

What colour is observed when ZnO is heated?

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59

In HCP of A, (1)/(3) of tetrahedral voids are occupied by B . What is the formula of the compound?

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60

Assertion : Due to Frenkel defect, there is no effect on the density of the crystalline solid. Reason : In Frenkel defect, no cation or anion leaves the crystal.

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61

In a crystalline solid, having formula XY_2 O_4 , oxide ions are arranged in cubic close packed lattice while, cations X are present is tetrahedral voids and cations Y are present

JIPMER 2018 Solution
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62

An atom forms face centred cubic crystal with density d=8.92 ~g / mL and edge length a=3.6 × 10^ -8 ~cm . The molecular mass of atom in amu is

JIPMER 2018 Solution
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63

Iron exhibits BCC structure at room temperature. Above 900 ^ ° C , it transforms to FCC structure. The ratio of the density of iron at room temperature to that at 900 ^ ° C is

NEET 2018 Solution
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64

ZnO is white when cold and yellow when heated. It is due to the development of

AIIMS 2017 Solution
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65

Assertion: The number of tetrahedral voids is double the number of octahedral voids. Reason: The size of the tetrahedral voids is half of that of the octahedral void.

AIIMS 2017 Solution
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66

A solid A B has NaCl structure. If the radius of cation A^ + is 170 pm , then the maximum possible radius of the anion B^ - is

JIPMER 2017 Solution
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67

A cubic unit cell of a metal with molar mass of 63.55 ~g ~mol^ -1 has an edge length of 362 pm . Its density is 8.92 ~g ~cm^ -3 . The type of unit cell is

JIPMER 2017 Solution
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68

Which is the incorrect statement?

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69

If an atom crystallises in b c c lattice with r=4 Å then the edge length will be

AIIMS 2016 Solution
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70

If oxide ions are arranged in hcp and the aluminium ions occupy two thirds of octahedral voids. What will be the formula of the compound?

JIPMER 2016 Solution
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71

In calcium fluoride, having the fluorite structure, the coordination numbers for calcium ion (C a ^ 2 + ) and fluoride ion ( F ^ - ) are

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72

Lithium has a bcc structure. Its density is 530kg m ^ - 3 and its atomic mass is 6.94gmo l ^ - 1 . Calculated the edge length of a unit cell of Lithium metal. ( N _ A = 6.02 × 10

NEET 2016 Solution
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73

The ionic radii of A ^ + and B ^ - ions are 0.98 × 10 ^ - 10 m and 1.81 × 10 ^ - 10 m . The coordination number of each ion in AB is

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74

The yellow colour in NaCl crystals is due to

AIIMS 2015 Solution
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75

Which of the following is an amorphous solid?

AIIMS 2015 Solution
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76

The Ca^ 2+ and F^ - are located in CaF_2 crystal respectively at face-centred cubic lattice points and in

AIIMS 2015 Solution
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77

Assertion : Conductivity of silicon increases by doping it with group-15 elements. Reason : Doping means introduction of small amount of impurities like P , As or Bi into the pure

AIIMS 2015 Solution
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78

Which of the following arrangements correctly represents hexagonal and cubic close packed structure respectively?

JIPMER 2015 Solution
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79

Ferrous oxide has a cubic structure. The length of edge of the unit cell is 5 Å and the density of the oxide is 4.0 ~g ~cm^ -3 . Then the number of Fe^ 2+ and O^ 2- ions present

JIPMER 2015 Solution
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80

The vacant space in bcc lattice unit cell is:

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81

The correct statement regarding defects in crystalline solids is :

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82

A given metal crystallizes out with a cubic structure having edge length of 361 pm. If there are four metal atoms in one unit cell, what is the radius of one atom?

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83

Assertion: Monoclinic sulphur is an example of monoclinic crystal system. Reason: For a monoclinic system, a ≠ b ≠ c and α=γ=90^ ∘ , β ≠ 90^ ∘ .

AIIMS 2014 Solution
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84

A forms h c p lattice and B are occupying 1 / 3^ rd of tetrahedral voids, then the formula of compound is

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85

Percentage of free space in a body centre cubic unit cell is

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86

If a the length of the side of a cube, the distance between the body centered atom one corner atom in the cube will be

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87

In a solid, atom M occupies ccp lattice and 1 / 3^ rd of tetrahedral voids are occupied by atom N . Find the formula of solid formed by M and N .

AIIMS 2013 Solution
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88

Assertion: The presence of a large number of Schottky defects in NaCl lowers its density. Reason : In NaCl , there are approximately 10^6 Schottky pairs per cm^3 at room

AIIMS 2013 Solution
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89

KF has ccp structure. How many F^ - ions and octahedral voids are there in this unit cell respectively?

JIPMER 2013 Solution
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90

The number of carbon atoms per unit cell of diamond unit cell is

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91

A metal has a fcc lattice. The edge length of the unit cell is 404 pm . The density of the metal is 2.72 ~g ~cm^ -3 . The molar mass of the metal is ( N_A Avogadro's constant

NEET 2013 Solution
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92

In b c c structure contribution of corner and central atom is

AIIMS 2012 Solution
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93

CsCl has b c c arrangement. Its unit cell edge length is 400 pm . Its inter-ionic distance is

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94

The number of atoms contained in a fcc unit cell of a monoatomic substance is

JIPMER 2012 Solution
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95

The number of octahedral void (s) per atom present in a cubic close-packed structure is

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96

Structure of a mixed oxide is cubic close packed (ccp). The cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent

NEET 2012 Solution
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97

A metal crystallizes with a face-centered cubic lattice. The edge of the unit cell is 408 pm . The diameter of the metal atom is

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98

Schottky defect is

AIIMS 2011 Solution
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99

Assertion : b c c and h c p has same packing efficiency. Reason : Both have same number of atoms per unit cell and same arrangement.

AIIMS 2011 Solution
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100

A solid compound X Y has NaCl structure. If the radius of the cation is 100 pm , the radius of the anion ( Y^ - ) will be

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101

Assertion : Due to Frenkel defect, density of the crystalline solid decreases. Reason : In Frenkel defect, cation or anion leaves the crystal.

AIIMS 2010 Solution
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102

In tetrag onal crystal system, which of following is not true?

AIIMS 2010 Solution
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103

A solid A B has the NaCl structure. If radius of cation A^ + is 120 pm , the maximum possible value of the radius of the anion B^ - is

JIPMER 2010 Solution
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104

If a be the edge length of the unit cell and r be the radius of an atom then for fcc arrangement, the correct relation is

JIPMER 2010 Solution
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105

A B crystallizes in a body centred cubic lattice with edge length ' a ' equal to 387 pm . The distance between two oppositively charged ions in the lattice is

NEET 2010 Solution
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106

Schottky defect in crystals is observed when

AIIMS 2009 Solution
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107

The figure shows elliptical orbit of a planet m about the sun S . The shaded area S C D is twice the shaded area S A B . If t_1 is the time for the planet to move from C to D and

NEET 2009 Solution
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108

Copper crystallises in a face-centred cubic lattice with a unit cell length of 361 pm . What is the radius of copper atom in pm ?

NEET 2009 Solution
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109

Lithium metal crystallises in a body centred cubic crystal. If the length of the side of the unit cell of lithium is 351 pm , the atomic radius of the lithium will be

NEET 2009 Solution
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110

Sodium has body centred packing. Distance between two nearest atoms is 3.7 Å . The lattice parameter is :

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111

Copper crystallizes in a face-centred cubic lattice with a unit cell length of 361 pm . What is the radius of copper atom in pm?

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112

Lithium metal crystallizes in a body centred cubic crystal. If the length of the side of the unit cell of lithium is 351 pm , the atomic radius of lithium will be :

NEET 2009 Solution
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113

Sodium has body centred packing. Distance between two nearest atoms is 3.7 Å . The lattice parameter is

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114

The flame colours of metal ions are due to

AIIMS 2008 Solution
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115

A unit cell of sodium chloride has four formula units. The edge length of the unit cell is \(0.564 ~nm\). What is the density of sodium chloride?

AIIMS 2008 Solution
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116

Total volume of atoms present in a face centred cubic unit cell of a metal is ( \(r\) is atomic radius)

JIPMER 2008 Solution
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117

Pure silicon doped with phosphorus is a

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118

Percentage of free space in a body centred cubic unit cell is

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119

Four diatomic species are listed below in different sequences. Which of these presents the correct order of their increasing bond order?

NEET 2008 Solution
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120

If the lattice parameter for a crystalline structure is 3.6 \% , then the atomic radius in fcc crystal is

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