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MHT CET 202623 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
23 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

MHT CET 2026 · 23 April · Evening Shift · Chemistry · Solutions

200 mL of an aqueous solution of a protein contain 1.26 g of...

200 mL of an aqueous solution of a protein contain 1.261.26 g of protein, the osmotic pressure of this solution at 300 K is found to be 2.57×10−32.57 \times 10^{-3} bar, Calculate the molar mass of protein. ( R = 0.083 bar mol^{-1}K−1K^{-1})

Options

  1. A5102.25102.2 g mol^{-1}
  2. B12204.412204.4 g mol^{-1}
  3. C3101131011 g mol^{-1}
  4. D6103961039 g mol^{-1}

Correct answer

D. 6103961039 g mol^{-1}

Step-by-step solution

Given:
Volume of solution, V=200V = 200 mL =0.200= 0.200 L
Mass of protein, W=1.26W = 1.26 g
Osmotic pressure, π=2.57×10−3\pi = 2.57 \times 10^{-3} bar
Temperature, T=300T = 300 K
Gas constant, R=0.083R = 0.083 L bar K^{-1}mol−1mol^{-1}

Using the formula for osmotic pressure:
π=WMVRT\pi = \dfrac{W}{M V} R T

Rearranging for molar mass MM:
M=WRTπVM = \dfrac{W R T}{\pi V}

Substituting the values:
M=1.26×0.083×3002.57×10−3×0.200M = \dfrac{1.26 \times 0.083 \times 300}{2.57 \times 10^{-3} \times 0.200}

M=31.3745.14×10−4M = \dfrac{31.374}{5.14 \times 10^{-4}}

M=61038.9M = 61038.9 g mol^{-1} \approx 61039gmol−1g mol^{-1}

Answer: 6103961039 g mol^{-1}
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