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MHT CET 202624 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
24 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

MHT CET 2026 · 24 April · Morning Shift · Chemistry · Thermodynamics (C)

What is the work done in the formation of 1 mole gaseous methane...

What is the work done in the formation of 1 mole gaseous methane from solid carbon and gaseous hydrogen at 27^{}^{\circ}\text{C}? (R=8.314 J k−1 mol−1R=8.314\ \text{J k}^{-1}\text{ mol}^{-1})

Options

  1. A−2.4942-2.4942 kJ
  2. B+2.4942+2.4942 kJ
  3. C−24.942-24.942 kJ
  4. D+24.942+24.942 kJ

Correct answer

B. +2.4942+2.4942 kJ

Step-by-step solution

The balanced chemical equation for the formation of 11 mole of gaseous methane is:

C(s)+2H2(g)→CH4(g)\text{C(s)} + 2\text{H}_2\text{(g)} \rightarrow \text{CH}_4\text{(g)}

The change in the number of moles of gaseous substances (Δng\Delta n_g) is:

Δng=ng,products−ng,reactants\Delta n_g = n_{g,\text{products}} - n_{g,\text{reactants}}

Δng=1−2=−1\Delta n_g = 1 - 2 = -1

The work done (WW) during a chemical reaction at constant temperature and pressure is given by:

W=−ΔngRTW = -\Delta n_g R T

Given:
R=8.314 J K−1 mol−1R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}
T = 27^{}^{\circ}\text{C} = 27 + 273 = 300 \text{ K}

Substituting the values:

W=−(−1)×8.314×300W = -(-1) \times 8.314 \times 300

W=+2494.2 JW = +2494.2 \text{ J}

W=+2.4942 kJW = +2.4942 \text{ kJ}

Answer: +2.4942+2.4942 kJ
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