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AIIMS2018ChemistryIonic Equilibrium

When 50 ~mL of 0.1 M NH ₃ is mixed with 10 ~mL of 0.1 M HCl then what is the pH of resultant solution? ( p K_b=4.75 )

Options

  1. A9.25
  2. B10
  3. C9.85
  4. D4.15

Correct answer

C. 9.85

Step-by-step solution

aligned & NH ₃+ HCl NH ₄ Cl & Initial 50 0.1 10 0.1 & =5 mmol =1 mmol & After 4 mmol 0 mmol 1 mmol & reaction & pOH = p K_b+ [ salt ] [ base ] & =4.75+ ( 1 4 )=4.15 & pH =14- pOH =14-4.15=9.85 & aligned

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