AIIMS2004ChemistryIonic Equilibrium
Assertion : Addition of silver ions to a mixture of aqueous sodium chloride and sodium bromide solution will first precipitate AgBr rather than AgCl . Reason : K_ s p of AgCl < K_ s p of AgBr
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion
- BIf both assertion and reason are true but reason is not the correct explanation of assertion
- CIf assertion is true but reason is false
- DIf both assertion and reason are false.
Correct answer
C. If assertion is true but reason is false
Step-by-step solution
K_ s p of AgCl >K_ s p of AgBr . For the precipitation to occur, its ionic product should exceed solubility product.