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NEET2009ChemistryCarboxylic Acid DerivativesActual

Consider the following reaction, Phenol Zn dust X Anhydrous AlCl ₃ CH ₃ Cl Y array l Alkaline KMnO array Z , the product, Z , is

Options

  1. Atoluene
  2. Bbenzaldehyde
  3. Cbenzoic acid
  4. Dbenzene

Correct answer

C. benzoic acid

Step-by-step solution

Key Idea (i) Z n dust converts - OH group into- H . (ii) Reaction with CH ₃ Cl in presence of anthy. AlCl ₃ is called Friedel-Craft's alkylation. (iii) Alkaline KMnO ₄ converts complete carbon chain which is directly attached with benzene ring, into - COOH group.

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