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NEET2023Chemistryd and f Block ElementsActual

The stability of Cu 2 + is more than Cu + salts in aqueous solution due to -

Options

  1. Asecond ionisation enthalpy.
  2. Bfirst ionisation enthalpy.
  3. Centhalpy of atomization.
  4. Dhydration energy.

Correct answer

D. hydration energy.

Step-by-step solution

The stability of Cu 2 +   ( aq ) rather than Cu +   ( aq ) is due to the much more negative ∆ hyd H o of Cu 2 +   ( aq ) than Cu +   , which more than compensates for the second ionisation enthalpy of Cu . The Cu 2 + ion has a greater charge density than Cu + ion and thus forms much stronger bonds releasing more hydration energy.

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