Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
NEET2023Chemistryd and f Block ElementsActual

Which of the following statements are INCORRECT? A. All the transition metals except scandium form MO oxides which are ionic. B. The highest oxidation number corresponding to the group number in transition metal oxides is attained in Sc 2 O 3 to Mn 2 O 7 . C. Basic character increases from V 2 O 3   to   V 2 O 4   to   V 2 O 5 . D. V 2 O 4 dissolves in acids to give VO 4 - 3 salts. E. CrO is basic

Options

  1. AB and C only
  2. BA and E only
  3. CB and D only
  4. DC and D only

Correct answer

D. C and D only

Step-by-step solution

Lower oxidation state oxides are ionic. The highest oxidation number in the oxides, coincides with the group number and is attained in Sc 2 O 3 to Mn 2 O 7 . The structure of V 2 O 5 is more covalent than that of V 2 O 3 and V 2 O 4 , which makes it more acidic. As a result, the basicity of V 2 O 5 is greater than that of V 2 O 4 , which is in turn greater than that of V 2 O 3 . Here in option C they have gien the increasing order of acidic character. So Option C is wrong. V 2 O 4 dissolves in acids to give VO 2 +

Practice d and f Block Elements on Quantrex Academy →

More from d and f Block Elements

Although +3 oxidation state is most common in lanthanoids, cerium still shows +4 oxidation state because : 2026The lanthanide ion having four unpaired electrons is (Given : Atomic numbers of Ce =58 , Nd =60 , Tb =65 and Ho =67 ) 2026The green paramagnetic species formed by heating KMn O₄ at 513 K is 2026The calculated 'spin-only' magnetic moment of Ti ²⁺ (3d^2) is : 2026Match List I with List II : List I (Transition metal/compound/complex) List II (Catalytic Role) A. V ₂ O ₅ I. Preparation of ammonia from N ₂/ H ₂ mixture B. Fe II. Polymerisation 2026Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R . Assertion A : Generally, 3d transition metals have high melting points. Reas 2026Given below are two statements : Statement I : Ferromagnetism is considered as an extreme form of paramagnetism. Statement II : The number of unpaired electrons in a Cr ²⁺ ion ( Z 2025Which of the following set of ions act as oxidising agents? 2024 Full d and f Block Elements list All NEET PYQs