NEET2002Chemistryd and f Block ElementsActual
Zn gives H ₂ gas with H ₂ SO ₄ and HCl but not with HNO ₃ because:
Options
- AZn acts as an oxidizing agent when reacts with HNO ₃
- BHNO ₃ is weaker acid than H ₂ SO ₄ and HCl
- Cin electrochemical series Zn is above hydrogen
- DNO ₃⁻ is reduced in preference to hydronium ion
Correct answer
D. NO ₃⁻ is reduced in preference to hydronium ion
Step-by-step solution
Nitric acid ( HNO ₃ ) is a strong oxidising agent. The Hydrogen gas produced during its reaction with metal gets oxidised to H ₂ O , hence no hydrogen gas is produced. Usually when Zn reacts with acid, it acts as a reducing agent which gets oxidised to a salt and the acid is the oxidising agent which gets reduced to hydrogen gas.