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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Ionic Equilibrium

NEET 2026 · Chemistry · Ionic Equilibrium

At 298 K, a certain buffer solution contains equal concentrations...

At 298298 K, a certain buffer solution contains equal concentrations of X−X^{-} and HXHX, KbK_b for X−X^{-} is 10−1010^{-10}. What is the pH of this buffer solution ?

Options

  1. A22
  2. B44
  3. C66
  4. D1010

Correct answer

B. 44

Step-by-step solution

Given KbK_b for X−=10−10X^{-} = 10^{-10}.

For a conjugate acid-base pair at 298298 K, Ka×Kb=Kw=10−14K_a \times K_b = K_w = 10^{-14}.

Ka=10−1410−10=10−4K_a = \dfrac{10^{-14}}{10^{-10}} = 10^{-4}

The pKapK_a of the weak acid HXHX is:

pKa=−log⁡(Ka)=−log⁡(10−4)=4pK_a = -\log(K_a) = -\log(10^{-4}) = 4

Using the Henderson-Hasselbalch equation for an acidic buffer:

pH=pKa+log⁡([X−][HX])\text{pH} = pK_a + \log \left( \dfrac{[X^{-}]}{[HX]} \right)

Since the concentrations of X−X^{-} and HXHX are equal, [X−]=[HX][X^{-}] = [HX].

pH=4+log⁡(1)=4+0=4\text{pH} = 4 + \log(1) = 4 + 0 = 4

Answer: 44
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