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NEET 2012
Exam
NEET
Year
2012
Subject
Chemistry
Chapter
Ionic Equilibrium

NEET 2012 · Chemistry · Ionic Equilibrium

Buffer solutions have constant acidity and alkalinity because

Buffer solutions have constant acidity and alkalinity because

Options

  1. Athese give unionised acid or base on reaction with added acid or alkali
  2. Bacids and alkalies in these solutions are shielded from attack by other ions
  3. Cthey have large excess of H+\mathrm{H}^{+}or OH−\mathrm{OH}^{-}ions
  4. Dthey have fixed value of pH\mathrm{pH}

Correct answer

A. these give unionised acid or base on reaction with added acid or alkali

Step-by-step solution

If small amount of an acid or alkali is added to a buffer solution, it converts them into unionised acid or base. Thus, its pHremainsunaffectedor\mathrm{pH}remains unaffected orin other words its acidity/alkalinity remains constant. e.g., H3O++A−⇌H2O+HA−OH+HA⟶H2O+A−\begin{aligned} \mathrm{H}_{3} \mathrm{O}^{+}+A^{-} \rightleftharpoons \mathrm{H}_{2} \mathrm{O}+\mathrm{H} A \\ & { }^{-} \mathrm{OH}+\mathrm{H} A \longrightarrow \mathrm{H}_{2} \mathrm{O}+A^{-} \end{aligned} If acid is added, it reactswithA−towith A^{-} toform undissociated HA. Similarly, if base/alkali is added, \mathrm{OH}^{-}combines with \mathrm{H}AtoA togive \mathrm{H}_2 \mathrm{O} and A−A^{-} and thus, maintains the acidity/ alkalinity of buffer solution.
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