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NEET 2002
Exam
NEET
Year
2002
Subject
Chemistry
Chapter
States of Matter

NEET 2002 · Chemistry · States of Matter

Under which conditions van der Waals real gas acts as an ideal gas?

Under which conditions van der Waals real gas acts as an ideal gas?Under which conditions van der Waals real gas acts as an ideal gas?Under which conditions van der Waals real gas acts as an ideal gas?

Options

  1. AHigh temperature, low pressure
  2. BLow temperature, high pressure
  3. CHigh temperature, high pressure
  4. DLow temperature, low pressure

Correct answer

A. High temperature, low pressure

Step-by-step solution

At high temperature and low pressure real gas acts as an ideal gas and obey p V=nRTp \mathrm{~V}=n \mathrm{RT} relation. for real gases, \left(p-\frac{n^2 a}{\mathrm{~V}^2}\right)(\mathrm{V}-n b)=RT<imgsrc="/api/proxy−image?url=https\mathrm{RT}<img src="/api/proxy-image?url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fneet%252FtnSPQPaGKIyV-orLMktKc3DKDVWEAsfhtnNW_Tkh7cY.original.fullsize.png%3Falt%3Dmedia&clean=1&v=wm2" data-qx-orig-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2FtnSPQPaGKIyV-orLMktKc3DKDVWEAsfhtnNW_Tkh7cY.original.fullsize.png?alt=media" data-qx-storage-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2FtnSPQPaGKIyV-orLMktKc3DKDVWEAsfhtnNW_Tkh7cY.original.fullsize.png?alt=media"> Van der Waals isotherms demonstrates the relationship between pressure, volume, and temperature based on the van der Waals model. The constants aa and bb have positive values and are specific to each gas. The higher the value of a, the greater the attraction between molecules and the more easily the gas will compress. The bb term represents the excluded volume of the gas or the volume occupied by the gas particles. The van der Waals equation becomes the Ideal Gas Law as these two correction terms approach zero.
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