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NEET2026ChemistryThermodynamics (C)Actual

Two moles of an ideal gas undergo free expansion from 10 L to 100 L at 300 K. The values of S_ system and S_ surroundings are (R is universal gas constant)

Options

  1. AS_ system =4.606 R; S_ surroundings =0
  2. BS_ system =0 ; S_ surroundings =0
  3. CS_ system =4.606 R; S_ surroundings =-4.606 R
  4. DS_ system =0 ; S_ surroundings =4.606 R

Correct answer

A. S_ system =4.606 R; S_ surroundings =0

Step-by-step solution

For the free expansion of an ideal gas, the external pressure is zero, so the work done W = 0 . Since the process is isothermal at 300 K, the change in internal energy U = 0 . From the first law of thermodynamics, q = U - W = 0 . Since no heat is exchanged with the surroundings, the change in entropy of the surroundings is: S_ surroundings = q_ surr T = 0 Entropy is a state function, so the change in entropy of the system for an isothermal expansion is calculated using a reversible path between the same initial and

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