NEET2025ChemistryThermodynamics (C)Actual
The standard heat of formation, in kcal / mol ^ of Ba ²⁺ is : [Given : standard heat of formation of SO ₄²⁻ ion (aq) =-216 kcal / mol , Standard heat of crystallisation of BaSO ₄( ~s )=-4.5 kcal / mol , standard heat of formation of . BaSO ₄( ~s )=-349 kcal / mol ]
Options
- A-128.5
- B-133.0
- C+133.0
- D+220.5
Correct answer
A. -128.5
Step-by-step solution
aligned & H _ crys ( BaSO ₄ )= H _ f ( BaSO ₄ )- [ H _ f ( Ba ⁺² )+ H _ f ( SO ₄⁻² ) ] & -4.5=[-349]- [ H _ f ( Ba ⁺² )+(-216) ] & H _ f ( Ba ⁺² )=-128.5 kCal ~mol ⁻¹ aligned