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NEET2012ChemistryThermodynamics (C)Actual

In which of the following reactions, standard reaction entropy changes ( S^ ) is positive and standard Gibb's energy change ( G^ ) decreases sharply with increasing temperature?

Options

  1. AC (graphite) + 1 2 O ₂(g) CO (g)
  2. BCO (g)+ 1 2 O ₂(g) CO ₂(g)
  3. CMg (s)+ 1 2 O ₂(g) MgO (s)
  4. D1 2 C (graphite) + 1 2 O ₂(g) 1 2 CO ₂(g)

Correct answer

A. C (graphite) + 1 2 O ₂(g) CO (g)

Step-by-step solution

Among the given reactions only in the case of C (graphite) + 1 2 O ₂( ~g ) CO ( g ) entropy increases because randomness (disorder) increases. Thus, standard entropy change ( S^ ) is positive. Moreover, it is a combustion reaction and all the combustion reactions are generally exothermic, i.e., H^ =- ve We know that aligned & G^ = H^ -T S^ & G^ =-v v -T(+ ve ) aligned Thus, as the temperature increases, the value of G^ decreases.

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