NEET2012ChemistryThermodynamics (C)Actual
In which of the following reactions, standard reaction entropy changes ( S^ ) is positive and standard Gibb's energy change ( G^ ) decreases sharply with increasing temperature?
Options
- AC (graphite) + 1 2 O ₂(g) CO (g)
- BCO (g)+ 1 2 O ₂(g) CO ₂(g)
- CMg (s)+ 1 2 O ₂(g) MgO (s)
- D1 2 C (graphite) + 1 2 O ₂(g) 1 2 CO ₂(g)
Correct answer
A. C (graphite) + 1 2 O ₂(g) CO (g)
Step-by-step solution
Among the given reactions only in the case of C (graphite) + 1 2 O ₂( ~g ) CO ( g ) entropy increases because randomness (disorder) increases. Thus, standard entropy change ( S^ ) is positive. Moreover, it is a combustion reaction and all the combustion reactions are generally exothermic, i.e., H^ =- ve We know that aligned & G^ = H^ -T S^ & G^ =-v v -T(+ ve ) aligned Thus, as the temperature increases, the value of G^ decreases.