NEET2006ChemistryThermodynamics (C)Actual
The enthalpy of hydrogenation of cyclohexene is -119.5 ~kJ ~mol ⁻¹ . If resoance energy of benzene is -150 kJ mol ⁻¹ , its enthalpy of hydrogenation would be:
Options
- A-358.5 ~kJ ~mol ⁻¹
- B-508.9 ~kJ ~mol ⁻¹
- C-208.1 ~kJ ~mol ⁻¹
- D-269.9 ~kJ ~mol ⁻¹
Correct answer
C. -208.1 ~kJ ~mol ⁻¹
Step-by-step solution
Heat of hydrogenation of cyclohaxene =-119.5 ~kJ / mol Heat of hydrogenation of benzene =3 -119.5=-358.5 ~kJ / mol Resonance energy = Observed H - Calculated H =-150.4=-358.5-xx=-208.1 ~kJ Related Theory The energy calculated for a resonance hybrid is lower than the energies of any of the alternative structures; the molecule is then said to be stabilized by resonance.